Thermochemical routes Second-generation biofuels
1 thermochemical routes
1.1 gasification
1.2 pyrolysis
1.3 torrefaction
thermochemical routes
carbon-based materials can heated @ high temperatures in absence (pyrolysis) or presence of oxygen, air and/or steam (gasification).
these thermochemical processes both yield combustible gas , solid char. gas can fermented or chemically synthesised range of fuels, including ethanol, synthetic diesel or jet fuel.
there lower temperature processes in region of 150–374 °c, produce sugars decomposing biomass in water or without additives.
gasification
gasification technologies established conventional feedstocks such coal , crude oil. second-generation gasification technologies include gasification of forest , agricultural residues, waste wood, energy crops , black liquor. output syngas further synthesis e.g. fischer-tropsch products including diesel fuel, biomethanol, biodme (dimethyl ether), gasoline via catalytic conversion of dimethyl ether, or biomethane (synthetic natural gas). syngas can used in heat production , generation of mechanical , electrical power via gas motors or gas turbines.
pyrolysis
pyrolysis established technique decomposition of organic material @ elevated temperatures in absence of oxygen. in second-generation biofuels applications forest , agricultural residues, wood waste , energy crops can used feedstock produce e.g. bio-oil fuel oil applications. bio-oil typically requires significant additional treatment render suitable refinery feedstock replace crude oil.
torrefaction
torrefaction form of pyrolysis @ temperatures typically ranging between 200–320 °c. feedstocks , output same pyrolysis.
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